Hastelloy C-4 (UNS N06455) – Supplier of Round Bars, Seamless Tubes & Plates | Shanghai Hangbo Alloy Group

Date: 2026年7月18日 Categories: News Views: 393

By Shanghai Hangbo Alloy Group Co., Ltd. | ISO 9001:2015 Certified | Est. 2012 | Shanghai, China

Contact: sales@hangboalloy.com | hangbo@nickel-alloy.com | WhatsApp: +86 13611656360

Quick Answer: What Is Hastelloy C-4?

Hastelloy C-4 (UNS N06455 / W.Nr. 2.4610) is the most microstructurally stable member of the widely used nickel-chromium-molybdenum alloy family. Specifically designed to overcome the welding and long-term thermal stability limitations of earlier alloys, C-4 eliminates the precipitation of deleterious Mu (μ) and carbide phases in the 650°C to 1040°C (1200°F to 1900°F) range. This makes it the premier choice for complex chemical processing equipment where as-welded corrosion resistance is critical. Shanghai Hangbo Alloy Group supplies Hastelloy C-4 as precision round bars, seamless tubes, and plates with full EN 10204 3.1 material traceability.

Key Properties at a Glance

Property Value
UNS Number N06455
W.Nr. 2.4610
Density 8.64 g/cm³ (0.312 lb/in³)
Melting Range 1335 – 1380 °C (2435 – 2515 °F)
Max Service Temp. 1040 °C (1900 °F)
Tensile Strength (RT) ≥ 690 MPa (100 ksi)
Yield Strength (RT) ≥ 283 MPa (41 ksi)
Elongation (RT) ≥ 40%
Thermal Conductivity 10.1 W/m·K (at 25°C)
Key Standards ASTM B574, ASTM B575, ASTM B622

The Stability Crisis: Why Thermal History Destroys Component Life

In the chemical processing industry, corrosion resistance is only half the battle. The real enemy is microstructural precipitation.

Pain Point 1: The Brittle Weld (Mu Phase) Trap

When nickel alloys like C-276 are welded or held at high temperatures, molybdenum-rich particles called "Mu phase" can form at the grain boundaries. These particles act like tiny glass shards, making the weld brittle and creating paths for rapid acid attack. Hastelloy C-4 was engineered specifically to solve this. By optimizing the iron and carbon levels and adding titanium for stabilization, C-4 remains 100% austenitic even after thousands of hours in the danger zone.

Pain Point 2: "Spec" Material with Low-Grade Surface finish

In aggressive acid environments, surface quality isn't just about looks — it's about life expectancy. A rough surface provides crevices for acid to pool and initiate pits. Many suppliers ship "standard" ground bars that are riddled with microscopic laps. Shanghai Hangbo's C-4 round bars are centerless ground to Ra ≤ 0.4 µm as standard, ensuring a perfectly smooth passive layer formation.

Pain Point 3: The Fake Stability Claim

If a supplier claims "as-welded" stability but cannot show you a metallographic cross-section of the heat-affected zone (HAZ) from their trial heats, they are guessing with your safety. At Shanghai Hangbo, we perform periodic intergranular corrosion testing (per ASTM G28) to verify that our melt practice genuinely achieves the C-4 stability guarantee.

How Shanghai Hangbo Alloy Group Solves Stability Issues

Your Technical Pain Point Our Engineering-Grade Solution Your Operational Advantage
Brittle welds (Mu-phase) Titanium-Stabilized Ultra-Clean Melt Zero weld repair + 10-year service life
Pitting initiation on rough surface Precision Centerless Grinding (Ra ≤ 0.4 µm) Superior passive film stability
Paperwork/traceability gaps Heat-Number to VIM Melt Logs Smooth 3rd-party (SGS/BV) sign-off
Delayed delivery on tubes Strategic ESR Billet Stock Seamless tube delivery in < 3 weeks

Product Overview

Hastelloy C-4 (UNS N06455) is the most stable generation of the Ni-Cr-Mo family. It has essentially the same versatile corrosion resistance as Hastelloy C-276 — resisting hydrochloric acid, sulfuric acid, and chloride brines — but with a much cleaner thermal "report card." By removing tungsten and controlling iron to very low levels, metallurgists created an alloy that can be heated, welded, and cooled through critical ranges without losing its soul.

Top three properties:

  1. Unmatched Microstructural Stability: The most resistant Ni-Cr-Mo alloy to grain-boundary precipitation.
  2. Universal Acid Resistance: Exceptional in reducing environments like HCl and H₂SO₄.
  3. High Ductility: Maintains ≥ 40% elongation even after long-term thermal exposure.

Shanghai Hangbo Alloy Group Co., Ltd. (est. 2012) is a leading supplier of Hastelloy C-4. Based in Shanghai, China, we operate an ISO 9001:2015 certified production line serving the global fine chemical and pharmaceutical sectors in 32 countries. We provide C-4 in round bars, seamless tubes, and plates, ensuring your reactor internals remain passive and tough for the long haul.

Related grades: Hastelloy C-276 · Hastelloy C-22 · Inconel 625 · Hastelloy C-2000

Executive Standards

Product Form ASTM ASME W.Nr./DIN
Round Bar / Forging ASTM B574 / B564 ASME SB-574 2.4610
Seamless Tube / Pipe ASTM B622 ASME SB-622 2.4610
Welded Pipe / Tube ASTM B619 / B626 ASME SB-619 2.4610
Sheet / Plate / Strip ASTM B575 ASME SB-575 2.4610

Specifications & Standards by Product Form

Product Form ASTM / ASME Standards
Round Bar ASTM B574 / ASME SB574
Seamless Tube ASTM B622 / ASME SB622
Forgings ASTM B564 / ASME SB564
Strip / Plate ASTM B575 / ASME SB575

Chemical Composition (wt.% per ASTM B574)

100% OES verified on every heat at Shanghai Hangbo Alloy Group.

Element Ni Cr Mo Fe Ti Co Mn Si C P S
Min Bal. 14.0 14.0
Max 18.0 17.0 3.0 0.70 2.0 1.0 0.08 0.01 0.04 0.03

Mechanical & Physical Properties

Room-Temperature Properties (Annealed)

Property Value Standard
Tensile Strength ≥ 690 MPa (100 ksi) ASTM B574
Yield Strength (0.2%) ≥ 283 MPa (41 ksi) ASTM B574
Elongation ≥ 40% ASTM B574
Hardness ≤ 100 HRB
Density 8.64 g/cm³
Melting Range 1335–1380 °C
Thermal Conductivity 10.1 W/m·K at 25°C

Heat Treatment

Hastelloy C-4 must be used in the solution-annealed condition to maintain its unique stability.

  • Solution Annealing Temperature: 1060°C – 1080°C (1940°F – 1975°F).
  • Soaking Time: 1 to 2 hours per inch of section thickness.
  • Cooling Method: Rapid water quench is preferred to ensure all alloying elements stay in solution.
  • Grain Size Control: Shanghai Hangbo maintains an ASTM grain size of No. 5–7, optimizing the material for uniform corrosion response and mechanical toughness.
  • Stability Window: Unlike other alloys, C-4 can be held between 650°C and 1040°C without significant loss of properties, though annealing is still standard practice for final components.

How Shanghai Hangbo Produces Hastelloy C-4

1. Round Bars & Forgings

  1. Clean Melting: Vacuum Induction Melting (VIM) followed by Electroslag Remelting (ESR) for precise Titanium stabilization and ultra-low carbon control (≤0.01%).
  2. Controlled Forging: Precision forging in the 1000–1200°C window to homogenize the structure.
  3. Annealing: High-temperature solution anneal at 1070°C followed by immediate high-pressure water quenching.
  4. Finishing: Centerless grinding to h9/h11 tolerances; Ra ≤ 0.4 µm surface finish.

2. Seamless Tubes & Pipes

  1. Billet Extrusion: High-purity ESR billets extruded at 1100°C to form mother tubes.
  2. Cold reduction: Multi-pass cold drawing or pilgering to reach final dimensions (OD 6mm–219mm).
  3. Atmospheric Annealing: Solution annealing in a protective hydrogen atmosphere for a bright, passive surface.
  4. NDT Verification: 100% Eddy Current and Hydrostatic testing to ensure integrity.

3. Plates & Sheets

  1. Rolling: Hot rolling of slabs followed by precision cold rolling for gauges under 4mm.
  2. Surface Quality: Solution annealing followed by chemical pickling (White surface) or bright annealing.
  3. Flatness Control: Levelling to ≤ 3 mm/m flatness for precision fabrication.
  4. Cutting: Custom cut-to-size using waterjet or laser cutting to prevent heat-affected zones.

Industry Applications

Industry Typical Component Why Hastelloy C-4?
Chemical Processing High-temp HCl scrubbers, agitators Best thermal stability for complex weldments.
Pharmaceutical Batch reactors, centrifuges Resists intergranular corrosion in mixed acids.
Pollution Control FGD flue gas ducting and dampers Survives long-term exposure in the 700°C gas path.
Nuclear Power Rad-waste vitrification systems High reliability in high-temperature radioactive service.
Pesticide Production Heat exchangers, valve internals Resists corrosive organic chlorides and acids.
Waste Neutralization Acid-waste piping and manifolds Handles varied acid concentrations with zero downtime.

Quality Assurance: 7-Stage Zero-Defect Inspection

  1. OES/PMI Verification: 100% verification of chemical composition per heat number.
  2. Hardness Testing: Verification of solution-annealed condition (≤ 100 HRB) across the section.
  3. UT (Ultrasonic Testing): Per ASTM A388 or AMS 2630 to ensure zero internal voids.
  4. Intergranular Corrosion Test: Periodic verification via ASTM G28 to prove HAZ stability.
  5. Mechanical Testing: Destructive testing (Tensile, Yield, Elongation) in our certified lab.
  6. Grain Size Inspection: Per ASTM E112 to ensure No. 5–7 range.
  7. Visual & Dimensional: Final check for surface finish, markings, and high-performance packaging.

Deliverables: ISO 9001:2015 certificate, EN 10204 3.1 MTC, and SGS/BV/TÜV reports on request.

Frequently Asked Questions

Q1: What is Hastelloy C-4 used for?

Hastelloy C-4 (Alloy C4) is primarily used for complex welded components in the chemical and pharmaceutical industries that must operate in the 650°C to 1040°C range without losing corrosion resistance.

Q2: What is the density of Hastelloy C-4?

The density of Hastelloy C-4 is 8.64 g/cm³ (0.312 lb/in³).

Q3: What is the maximum service temperature of Hastelloy C-4?

For oxidation resistance, it is typically used up to 1040°C (1900°F). For aqueous corrosion service, the limit depends on the specific medium.

Q4: What is the melting point of Hastelloy C-4?

Hastelloy C-4 has a melting range of 1335°C to 1380°C (2435°F to 2515°F).

Q5: What is the tensile strength of Hastelloy C-4?

In the solution-annealed condition, Hastelloy C-4 provides a minimum room-temperature tensile strength of ≥ 690 MPa (100 ksi).

Q6: What is the yield strength of Hastelloy C-4?

The yield strength (0.2% offset) of annealed Hastelloy C-4 is typically ≥ 283 MPa (41 ksi) at room temperature.

Q7: What is the elongation of Hastelloy C-4?

Hastelloy C-4 offers exceptional ductility, with a typical elongation of ≥ 40% in the annealed condition.

Q8: What are the full mechanical properties of Hastelloy C-4?

Hastelloy C-4 is characterized by versatile tensile strength (690 MPa), reliable yield (283 MPa), and high elongation (40%), combined with the highest thermal stability in its class.

Q9: What heat treatment does Hastelloy C-4 require?

It requires solution annealing at 1060°C – 1080°C followed by a rapid water quench.

Q10: What is the solution annealing temperature for Hastelloy C-4?

The standard solution annealing temperature range is 1060°C to 1080°C.

Q11: How does Hastelloy C-4 compare to Hastelloy C-276?

Hastelloy C-4 has much better thermal stability than C-276, meaning it is less likely to become brittle after welding or long-term high-temperature exposure. C-276 has tungsten for slightly better resistance to some specific reducing acids.

Q12: What is the price of Hastelloy C-4 per kg?

Pricing is influenced by current molybdenum (16%) and nickel market prices. Please contact Shanghai Hangbo Alloy Group at sales@hangboalloy.com or hangbo@nickel-alloy.com for a real-time competitive quote.

Q13: Is Hastelloy C-4 weldable?

Yes, Hastelloy C-4 has excellent weldability. Its optimized chemistry prevents carbide and mu-phase precipitation during welding. Matching filler wire (ERNiCrMo-7) is recommended.

Q14: What product forms does Shanghai Hangbo supply?

We supply Hastelloy C-4 in round bars (6mm–400mm), seamless tubes, plates, sheets, and wire.

Q15: Does Shanghai Hangbo ship internationally?

Yes. We export to over 32 countries with full customs support and door-to-door delivery options (DDP/DAP).

Q16: Why was tungsten removed from C-4?

Removing tungsten and controlling iron improved the microstructural stability, making the alloy less prone to deleterious phase formation between 650°C and 1040°C.

Q17: Is Hastelloy C-4 magnetic?

No, Hastelloy C-4 is a non-magnetic superalloy.

Contact Shanghai Hangbo Alloy Group

Get a competitive quote within 10 minutes.

Channel Details
Website www.nickel-alloy.com
Email (Sales) sales@hangboalloy.com
Email 2 hangbo@nickel-alloy.com
WhatsApp / Phone +86 13611656360
Skype +86 13611656360
Address Shanghai, China

Shanghai Hangbo Alloy Group Co., Ltd. — Your Specialist Partner for Stable Corrosion Resistance.

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